Abstract Recently more than 150 million tonnes of plastics were produced in the world. On the one hand, the consumption and production of polymers are increasing, on the other hand as landfill and incineration become more expensive and less accepted .The increasing amount of polymer wastes from them generates further mainly environmental problems. The recycling of plastic wastes is gaining increasing importance. Pyrolysis is one promising method for the treatment of mixed and contaminated plastic wastes. In this way the plastic wastes are converted into fuels or other valuable feedstock for the petrochemical industry. In present work catalytic cracking of waste plastics blend with HGO [Libyan gas oil supplied by the Zawia Oil Refinery Company boils in the range of 275-375Cº] was investigated using H-ZSM5and H-BETA. Reaction systems that were studied included high density polyethylene HDPE and polypropylene blend with HGO, reactions were carried out in one litre micro autoclave reactor under different conditions of weight, temperature and type of catalyst, The optimum conditions were 2.5% catalyst by weight of total feed stock, one hour, atmospheric presser and three temperatures selected 400Cº, 425Cº and 450Cº. The product distribution for the system [plastics and HGO] provided some good results high yield of liquid [gasoline] up to 210Cº, gases and small amount of heavy oils. Some analysis was used to qualify and quantify the product. The results from GC.MS analysis showed that the yield of gasoline (c5-c12) over H-ZSM5 higher than H-BETA. In case of 5%PP, 15%HDPE and 80%HGO over H-ZSM5 at 450Cº, 96% total conversion achieved. The result from TGA in the same case is 15% by weight. Also the theoretical calculations to quantify the produced gases after burring of waste plastic in rotary kiln reactor have been evaluated. it is found that the suitable ratio of CO:H2 to produce methanol is 7:1
بسمة محمود التونسي (2010)

Abstract Here asphaltene precipitation in petroleum reservoirs during natural depletion and miscible gas injection is modeled for two distinct and new methods (polymer solution and Scott-Magat theory). The first model is based on the polymer solution theory, which is a combination of Miller's combinatorial term with a modified residual term of the original Flory-Huggins theory. The second one is based on the Scott Magat theory to represent solid-liquid equilibria. The models has also been coupled with Peng Robinson equation of state (PR EOS) to describe the phase behavior of asphaltene compounds in crude oil and predict the amount of asphaltene precipitation during injection of carbon dioxide for the miscible displacement of asphaltic crudes. The model treats asphaltene within crude oil as a single pseudocomponent represented by an average molecular weight and molar volume and solubility parameter . The results of both models show an acceptable and good agreement between the real data (field and experimental) and those of the models. As it can be seen from the obtained results of those of the two models, it seems that application of the lattice or polymer solution theories (based on The Miller's combinatorial term) could give better results that are more close to real data.
وداد بلعيد حميدات (2009)

Abstract Water contamination is one of the major problems which the world is facing today. Water contamination not only effect environment and human health, but it has also impacts on economic and social costs. There are various ways used commercially and non- commercially to fight this problem which is advancing day by day due to technological progress There are many methods used for wastewater treatment, among these methods, the use of biological filters " trickling filter ", which depends on The basic idea is to get a larger surface area to get a better handle on the percentage. A composite media is used to replace the conventional stone in order to improve wastewater treatment in this thesis. The aim of this thesis to improve the performance of biological filters using nanotechnology, where to enhancing polymer media in biological and reinforced polypropylene by carbon fiber filters and talc by using electro spinning technology to produce the reinforced fiber that outlet from extruder. Design and simulate the extruder / die characteristics and studying The drag flow and pressure flow were then extracted from the screw parameters which lead into the calculation of the operation point and the operating pressure for the die. Also studying the effect of pressure and viscosity. Calculation of , and extruder characteristic is performed in order to allocate the operating point of the extruder.Two brand of carbon fiber are used in this thesis. The chapter type is at A tensile strength of 800 MN/m2. is selected. The operating pressure of the extruder is found to vary form 29.8 to 38.95 MN/m2 at an operating flow rate of 1.52*10-5 m3/sec. depending on the percentage of carbon fiber used in the blend.
محمود عيسى الفاما (2015)