الهدف الأساسي من هذا المشروع هو تحضير بعض 4-ثيازوليدينونات مستبدلة وتطوير طريقة جديدة لتحضير مشتقات ثيوفين.قمنا بتحضير بعض مشتقات 4-ثيازوليدينونات معروفة وجديدة بتفاعل مركبات ميثيلين نشطة مختلفة (201a-g) مع فينيل أيزوثيوسيانات في دايكوسان في وجود مسحوق جاف من هيدروكسيد البوتاسيوم عند 0-5oC ومعالجة أملاح بوتاسيوم كيتين N، S-- أسيتال الناتجة (202a-g) مع إيثيل كلوروأسيتات ليعطي (203a-g) وقد استخدمت 4-ثيازوليدينونات المحضرة 203a-f)) كمواد بادئة لتفاعلات وتحولات أخرى. حضرت في هذه الدراسة مركبات جديدة (206a-c) بازدواج ملح الديأزونيوم لبارا تولويدين (205) مع 4-ثيازوليدينونات (203a,d,f) ليعطي مشتقات 5-ديازينيل-4- ثيازوليدينونات ((206a-c وقد تفاعلت مشتقات الثيازوليدينون (203a، b، d، f) مع ألدهيدات متنوعة (207a-c) وتم الحصول على مشتقات 5,2 –ثنائي أيليدين (208a-d). لقد جرى سابقا تحويل (203a) بنجاح إلى مشتقات ثيوفين إستر عند تفاعلها مع كحولات وثيوفين أميد عند تفاعلها مع الأمونيا. وكاستمرار لهذا تمت دراسة تفاعلات الكحولات مع 4-ثيازوليدينونات متنوعة لتحويلها إلى مشتقات ثيوفين-2-كربوكسيلات، فقد تفاعل مشتق ثنائي سيانو 4-ثيازوليدينون (203a) بنجاح مع كحول ايزوبيوتيل وأعطى 3-أمينو ثيوفين -2-كربوكسيلات (211a). ولكن هذا الكحول فشل في تحويل بقية 4-ثيازوليدينونات (203b-f). أما المركبين (203d، e) فقد تفاعلا مع الإيثانول بنجاح تحت مكثف راد في وجود ثلاثي إيثيل أمين كحفاز لتعطيا نفس الناتج (211b). وهذا له دلالات كبيرة في تحديد التشكل الهندسي للثيازوليدينون البادئ وميكانيكية التفاعل. ومن جهة أخرى تفاعل مركب (203f) مع الإيثانول تحت مكثف راد ليعطي ثيوفين -4,2-ثنائي كربوكسيلات (211c). كما أدت معالجة مركبات 4-ثيازوليدينونات (203b-c) بالأمونيا إلى تكوين مشتقات ثيوفين كربوكساميد (211a-b) بميكانيكية مشابهة وذات أهمية في تحديد التشكل الهندسي أيضا. ولقد أعطى تفاعل التكثيف لمركب (209a) مع ألدهيدات أروماتية مثل بنزالديهايد وبارا نيتروبنزالديهايد في وجود كبريتات الصوديوم اللامائية مشتقات أزوميثين (218a,b ) . أما ثيينوبيريميدينونات الجديدة (219a-d) فقد تم تحضيرها في هذه الدراسة بتفاعل مركب (209a) مع عدد من الألدهيدات الأروماتية تحت مكثف راد في حمض اسيتيك ثلجي. ومن جهة أخرى تحولق مركب الديازونيوم من (209a) وأعطى مشتقة ثيينو-ترايازينون(221) بدل من الأزيد المتوقع (222) وأخيرا أدى تفاعل 3-أمينوثيوفين-2-كربوكسيليت (210b) مع ثلاتي إيثيل أورثوفورميث إلى تكوين (223). Abstract The main goal of this research project i to synthesize some substituted 4-thiazolidinone and to develop new routes for synthesis of thiophene derivatives. We synthesized some known and novel 4-thiazolidinones by reacting different active methylene compounds (201a-g) with phenylisothio cyanate in dioxane in the presence of dried powder potassium hydroxide at 0-5oC , and treating the resulting ketene-N,S-acetals potassium salts (202a-g) with ethylchloro acetate to give (203a-g). The synthesized 4-thiazolidinones (203a-f) were used as starting materials for further reactions and transformations. In this study novel compounds (206a-c) were prepared by coupling diazonium salt of p-toulidine (205) with 4- thiazolidinone derivatives (203a, d, f), to give 5-diazenyl- 4-thiazolidinone derivatives (206a-c). Thiazolidinone derivatives (203a, b, d, and f) were reacted with a variety of aldehyds (207a-c), to give the corresponding 2, 5-diylidiene derivatives (208a-d). Conversion of 2-ylidene-3-phenyl- 4-thiazolidinones into thiophene-2-carboxylate derivatives was attempted. While compounds (203b-f) did not react with isobutyl alcohol, dicyano derivative (203a) was successfully transformed into 3-aminothiophene carboxylate (211a). Refluxing compounds (203d, e) in ethanol in the presence T.E.A as catalyst gave the same product (211b) .This result is significant in determining the geometry of the starting 4-thiazolidinone and in the mechanism of these transformations. On the other hand, compound (203f) on refluxing with ethanol afforded the thiophene-2, 4-dicarboxylate (211c). Treatment of compounds (203b-c) with ammonia afforded the thiophene carboxamide derivatives (211a-b), involving similar mechanism and significance in geometrical determination of the starting 4-thiazolidinones. The condensation reaction of compound (209a) with aromatic aldehydes in presence sodium sulfate gave the azomethine Schiff base derivatives (218a, b). Some of novel thienopyrimidinone (219a-d) have been synthesized in this work by refluxing compound (209a) with some aromatic aldehyde in glacial acetic acid On the other hand diazonium solution of compound (209a) cyclized into thieno triazinone derivative (221) rather than expected compound (222). The 3-amino thiophene- 2-carboxylate (210b) was refluxed with triethylortho formate to produce compound (223).
نسرين أبو غرارة محمد دويئة (2014)

Abstract The Sarir Sandstone in Messla Oil Field are of Lower Cretaceous ageAptian Alpian and occur in the subsurface of the eastern part of the Messla high in the southeast Sirt Basin. The Sarir Sandstone interpret as fluvial and alluvial fan deposits whereas the Lower Sarir Sandstone were deposited in a braided system as inter-channel bars. The Upper Sarir Sandstone were deposited in the meandering belt of the fluvial system. The Sarir Sandstone is on-lapping Formation and wedge out against Rakb Group. The Sarir Sandstone is unconformable overlies the Pre-Cambrian Basement and unconformable overlain by the Upper-Cretaceous Rakb Group where it is pinching (wedging) out against the Bald Basement; Messla High)). Lithostratigraphic correlations of borehole logs ((well logs)) in concession 65 suggests that deposits gradually downed a fault controlled topographic surface increased in thickness on the down-thrown side of a fault controlled the topographic surface of Pre-Upper Cretaceous Unconformity. IV M. Sc. Hassin Haweel “Sedimentological Aspects of the Sarir Sandstone in Messla Oil Field”, 2015 Core Samples record mainly sandstone units interbedded with sandstone and shale and minor streaks and the Red Shale Unit. Estimation of depositional environment has thus been made from grain size analyses using thin sections. Petrographic studies show that the Sarir Sandstone in composition from (subarkose to arkosic arenite). The Sandstones range from texturally immature to submature, however, much of the clay content is diagenetic in origin and not a function of the depositional regime. Diagenetic studies reveal a gnite complex paragenesis. During early diagenesis, the Sarir Sandstones were modified by Calcite, dolomite, and locally pyrite, diagenesis process; replacements of corroded silica by carbonates. Cementation fluvial sandstones Intrastratal dissolution and precipitation of kaolinite in the resulting pore space. Deformation of micas between more resistant grainy pre-dates one phase of quartz overgrowth, probably the carbonates.The purpose of this study was to investigate in detail the characteristics of the Sarir Sandstone in Messla Oil Field. Another aim was to find out the relation to the adjacent area. The method of this study was conducted with the review of the previousworks in Messla Oil Field; published papers, the open file of the Arabian Gulf Oil Company (AGOCO), well files for the data to be used in constructing maps, cross sections and profiles. Four cored wells (418 feet) V M. Sc. Hassin Haweel “Sedimentological Aspects of the Sarir Sandstone in Messla Oil Field”, 2015 were used for the core descriptions and cut samples that represent the Sarir Sandstone and (130) thin sections were used for the Petrographic analysis with polarized and scanning electron microscopes (SEM). On the other hand, XRD and XRF were not available. The results of the study were: Subsurface investigations including cores (conventional and side walls), petrographic analysis, and wire-line logs suggested that this formation (Sarir Sandstone) can be divided in to three main units in Messla Oil Field; these units are: The Lower Sarir Sandstone, the Red Shale, and the Upper Sarir Sandstone. In the adjacent area Sarir Formation was divided in to five members; Pre-Upper Cretaceous Member-1 unconformably overlying Pre-Cambrian Basement, and upwards; Member 2, Member 3, Member 4, and Member 5 unconformably overlain by Rakb Group. The Lower Sarir Sandstone in Messla Oil Field is characterized by the presence of gravely sandstone, gradually changes in to the Red Shale. Also, from the core descriptions plotted sheets, and the well logs it is finning upwards. The quarzitic sandstones of (the Lower and the Upper Sarir Sandstones) are considered to be the main producing horizons where quartz grains have undergone a complex diagenetic history, including: Authigenesis, quartz and feldspar overgrowths, dissolution, carbonates cementation, and replacement. The principal conclusion was that: the gravelly sandstone unit at the Lower part of the Lower Sarir Sandstone was deposited, most likely in a braided system as inter-channel bars. The sandstone unit of the Upper Sarir VI M. Sc. Hassin Haweel “Sedimentological Aspects of the Sarir Sandstone in Messla Oil Field”, 2015 Sandstone was deposited in the meandering belt of the fluvial system. The shale facies of the Red Shale unit represents a well-developed break between the Lower Sarir Sandstone and Upper Sarir Sandstone units; it also provides a good seal for the underlying sandstone of the Lower Sarir Sandstone. The nature of the shale facies, (i.e. lack of organic content, and presence of oxidizing conditions indicated by iron oxides color, indicate that they are not a significant source of hydrocarbons. On the other hand, the Rakb Shale isthe only source rock in the studied and adjacent areas.
حسين محمد علي حويل (2015)

في هذا البحث ناقشنا بعض المفاهيم ومنها وصلنا إلى مفهوم دالة التمثيل الخطي المحدودة بين جبران بوليان وأخيرا أثبتنا جبريا نظريتا كالتن للتمثيل الخطي المحدود بالأبواب التالية: الباب الأول: قدمنا في هذا الباب بعض التعريفات والقواعد والنتائج الأساسية التي نحتاجها لاحقا. مثل نظرية المجموعات ومجموعة كانتور ومجموعات بوريل. الباب الثاني: ناقشنا في الباب الثاني بعض المفاهيم المتعلقة بالجبر البولي والمؤثر الخطي المحدود بين جبران بوليان. الباب الثالث: أما الباب الثالث فقد ناقشنا فيه المفاهيم المتعلقة بالقياس والقياس المؤشروالمجموعات القابلة للقياس والدوال المقيسة والتكامل بالنسبة للقياس المؤشر وأخيرا عرفنا فضاء . الباب الرابع: قدمنا النتيجة الأساسية لهذا البحث وهي الإثبات جبريا نظريتا كالتن للتمثيل الخطي المحدود. Abstract In this thesis, we give an algebraic proof of the Kalton representation theorems. In chapter one, we give some basic standard definitions and some results we need later. In chapter two we discuss the concept of Boolean algebra, and bounded linear operators between two Boolean algebras. In chapter three, we discuss the concepts of measure, signed measure, measurable sets, measurable functions, integration with respect to signed measure; later in this chapter, we define.In the last chapter (4) we give the main result of our thesis which is the proof of KALTON representation theorems.
إيمان إسماعيل النحائسي (2010)